Toxic Exposure Research and Military Family Support Act of 2014 - Directs the Secretary of Veterans Affairs to:
Requires the Center, in coordination with the National Birth Defect Registry, to track and research the genetic link between individuals who are exposed to Agent Orange and the medical conditions of their children.
Extends eligibility for medical care and caregiver assistance to descendants of a veteran who was exposed to toxic substances while serving as a member of the Armed Forces if: (1) the descendant has a health condition resulting from exposure to toxic substances and is homebound due to such condition, and (2) the veteran has or had the same health condition.
Authorizes the Secretary of Defense (DOD) to declassify documents (other than documents that would materially and immediately threaten national security) related to any known incident in which not less than 100 members of the Armed Forces were exposed to a toxic substance that resulted in at least one case of disability.
Directs the VA Secretary, the Secretary of Health and Human Services (HHS), and the DOD Secretary to jointly conduct a national outreach and education campaign directed at members of the Armed Forces, veterans, and their family members to communicate information on incidents of exposure to toxic substances, health conditions resulting form such exposure, and the potential long-term effects of such exposure.